I'm more of a brownie person, actually. – Always lightning. The Blue Cake fires a lightning orb in a slightly arching trajectory that explode on impact, dealing Lighting Splash Damage. At a set distances the lightning orb explodes and splits into 2. This occurs twice totaling 4 lightning orbs after the last split.
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The weapon's name and flavor text reference "yellowcake," an intermediate product of uranium enrichment and the namesake of a legendary rocket launcher in Borderlands 3 with a similar flavor text joke.